Ionic Conductivity of LiHf2(PO4)3 with NASICON-type Structure and its Possible Application as Electrolyte in Lithium Batteries
نویسنده
چکیده
Este trabalho reporta medidas de condutividade iônica realizadas para o LiHf2(PO4)3 calcinado a 1100 °C. As respostas devidas aos grãos in te rior e junção puderam ser identificadas tanto nas curvas de impedância, como na parte real das curvas de condutividade vs. freqüência. A energia de ativação, associada ao movi men to dos íons Li no in te rior dos grãos, é 0,33 eV, enquanto que aquela associada à condutividade to tal cc, está na faixa de 0,36-0,47 eV. os resultados desta última dependem da contribuição relativa devida ao in te rior e à junção de grão. A possível aplicação do LiHf2(PO4)3 como eletrólito foi testada para a pilha Li/LiHf2(PO4)3/LiMn2O4. Observou-se que o potencial de equilíbrio aumenta de 0,076 V a 2,217 V, quando a temperatura varia de 28 a 148 °C.
منابع مشابه
Preparation, characterization and stability of Li-ion conducting Li1.5Al0.5Ge1.5(PO4)3 glass-ceramic with NASICON-type structure
A conducting lithium aluminum germanium phosphate (LAGP) glass-ceramic with a formula of Li1.5Al0.5Ge1.5(PO4)3 was synthesized by melt-quenching method and subsequent crystallization at 850 °C for 8 h. The prepared glass-ceramic was characterized using differential scanning calorimetry (DSC), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and AC impedance techniqu...
متن کاملHigh Lithium-Ion-Conducting NASICON-Type Li1+xAlxGeyTi2−x−y(PO4)3 Solid Electrolyte
A water-stable solid electrolyte is a key material without which aqueous lithium–air batteries could not be operated. In this study, we have examined the electrical conductivity and mechanical properties of a water-stable lithium-ion-conducting solid electrolyte, Li1+xAlxGeyTi2−x−y(PO4)3 with the NASICON-type structure, as a function of the Al and Ge content. Li1+xAlxGeyTi2−x−y(PO4)3 was synthe...
متن کاملPreparation of NASICON-Type Nanosized Solid Electrolyte Li1.4Al0.4Ti1.6(PO4)3 by Evaporation-Induced Self-Assembly for Lithium-Ion Battery
A simple and practicable evaporation-induced self-assembly (EISA) method is introduced for the first time to prepare nanosized solid electrolyte Li1.4Al0.4Ti1.6(PO4)3 (LATP) for all-solid-state lithium-ion batteries. A pure Na+ super ion conductor (NASICON) phase is confirmed by X-ray diffraction (XRD) analysis, and its primary particle size is down to 70 nm by optimizing evaporation rate of th...
متن کاملساخت شیشه- سرامیک هادی یون لیتیوم با هدایت یونی بالا برای ساخت باتریهای لیتیوم- اکسیژن و یون- لیتیوم تمام جامد
In this research, new lithium ion conductor glass-ceramics with NASICON-type structure (Li1+x+yAlxCryGe2-x-y (PO4)3, x+y=0.5) were synthesized using melt-quenching method and converted to glass-ceramics through heat treatment. Influence of addition of different concentrations of aluminum and chromium in LiGe2(PO4)3 glass-ceramic was investigated for ionic conduction improvement. Substitution of...
متن کاملRecent Advances in Inorganic Solid Electrolytes for Lithium Batteries
Present address: Xiao-Liang Wang, Seeo, Inc., 3906 Trust Way, Hayward, CA 94545, USA The review presents an overview of the recent advances in inorganic solid lithium ion conductors, which are of great interest as solid electrolytes in all-solid-state lithium batteries. It is focused on two major categories: crystalline electrolytes and glass-based electrolytes. Important systems such as thio-L...
متن کامل